|
|Section2= |Section3= |Section7= |Section8= }} Tungsten(IV) sulfide is the chemical compound with the formula WS2. It occurs naturally as the rare mineral called tungstenite. This material is a component of certain catalysts used for hydrodesulfurization and hydrodenitrification. WS2 adopts a layered structure related to MoS2, with W atoms situated in trigonal prismatic coordination sphere. Owing to this layered structure, WS2 forms inorganic nanotubes, which were discovered on an example of WS2 in 1992.〔 ==Properties== Bulk WS2 forms dark gray hexagonal crystals with a layered structure. Like the closely related MoS2, it exhibits properties of a dry lubricant. It is chemically fairly inert but is attacked by a mixture of nitric and hydrofluoric acids. When heated in oxygen-containing atmosphere, WS2 converts to tungsten trioxide. When heated in absence of oxygen, WS2 does not melt but decomposes to tungsten and sulfur, but only at 1250 °C.〔 The material undergoes exfoliation by treatment with various reagents such as chlorosulfonic acid.〔http://pubs.acs.org/doi/abs/10.1021/jz300480w〕 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Tungsten(IV) sulfide」の詳細全文を読む スポンサード リンク
|